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Radio Times 43 Is 22a Snout?

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Sandy-Wroe | 14:03 Tue 13th Oct 2009 | Crosswords
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It's a slang word for tobacco, but what has it to do with tin?
22a Tin appearing for tobacco(5) - N - U -

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Sn is the symbol for tin in the periodic table.
SN is the chemical abreviation for the metal TIN
Sn = formula for tin
Out = appearing
sn is element for tin would suggest out is appearing
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