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izzieamy | 19:20 Thu 11th Sep 2008 | Education
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Everyday temperature scales go lower than zero. why isnt it possible to have a measurement of heat that is lower than zero ?

thank you

this has been bugging me X
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The following is a very simplified version of the science but, without getting into university-level quantum physics, it will (hopefully) suffice.

The molecules in all solids are not at rest. They're vibrating. It's the energy from these vibrations which is perceived as 'temperature'. Additional energy can be added by, for example, placing the solid in a flame, which results in the greater molecular movement (i.e. a higher temperature). If enough energy is applied, the bonds between the molecules start to break down and the solid becomes a liquid. Adding yet more energy (heat) means that the molecular activity is sufficient for individual molecules to break free from their neighbours, as the liquid becomes a gas.

Going the other way, as we remove energy (heat) from any substance, the molecular activity decreases. (i.e. the temperature drops). Eventually there comes a point at which there is no molecular movement whatsoever, so the temperature is as low as it can possibly go. This temperature is defined as (absolute) zero on the Kelvin scale. (i.e. 0K)

A temperature lower than 0K would have to refer to a level of molecular activity which is less than 'not moving at all'. Clearly, that's impossible, so nothing can ever be at a temperature below 0K.

Chris
Buenchico's answer is impressive as always. The answer talks about 0 deg K which is around -273K if my memory serves me correctly.
But please could Izzieamy clarify the question because it seems unclear to me- it says scales go below zero and tehn says why can't we measure below zero. Is she asking why when we measure ice it appears as 0 degrees C, as this was answered only last week on this site

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