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Nothing to do with the sea. Light from the sun is scattered by the dust, pollen, etc. in the atmosphere. Blue light, because of its shorter wavelength, is scattered more than the other colours, causing the whole of the sky to look blue. Other colours travel to us more directly, which is why the sun itself looks white - or slightly yellow because some of the direct blue is missing through scattering.
At sunrise and sunset, because the sun is so low on the horizon, the light comes to us through a far thicker chunk of atmosphere. This absorbs the blue entirely and only the red can get through.
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