Brownies - Gems or Precious Metals

The clue is "Look inside to find London river & knot" (8 letters)" Can anyone help or advise me what gem or precious metal answers the clue ?
17:59 Fri 24th Feb 2012
 
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platinum
sorry wrong one amethyst
Explain?
Question Author
Thank you for replying clairerob21, but, like Quizmaster, I do not see how you arrive at your suggested answer of "amethyst". Your further remarks will be welcomed.
Question Author
For Quizmaster, please read Quizmonkey, above.
http://www.gemselect....nfo/gemstone-list.php

maybe peruse the above for ideas?
Mix up the letters to get thames, that leaves ty - eg knot (tie it up)
Question Author
Sorry to have doubted you and queried you, clairerob21, but the "penny has dropped", with the further help of cathfromsaron and red-berry.I thank you all.

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