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Don't use a silicone cake tin for anything special, I have loads and whilst they are usually ok, sometimes you can't get the cakes out. Regarding your other cake tin - first grease it, then line it with non stick parchment, your cake will turn out a treat.
Why would you use any kind of cake mix at all? Chocolate sponge is very easy to make. Use a Victoria sandwich recipe, but use a mixture of 25% cocoa powder to every 75% flour (3oz flour pus 1oz cocoa ). Don't use drinking chocolate powder as this has sugar added to it. The cake batter will look quite pale in the bowl, but is lovey and chocolatey when cooked. Good Luck!!!
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