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The answer is here: http://www.wpbschoolhouse.btinternet.co.uk/pag e03/3_31rates.htm Look to see how concentration effects reaction rate
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In a nutshell, the rate of reaction depends on the number of collisions (between the reacting species) per unit time that have the required energy to cause a reaction that leads to the products. As the concentrations of the reacting species decrease, so the frequency of these collisions decreases also, hence the reduce rate of reaction.
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