Sat Times Cryptic No.977 22dn and 16 ac

Can someone please explain?
16ac- English worker holding up Bishop to be heretical (6) . It must be "errant" but where does the "rr" come from?
22dn- He and I are two live wires(8). This looks like elements but I'm unsure of the reasoning.
Many thanks in advance.
14:03 Sun 29th Apr 2012
 
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rr...Right Reverent
He (helium) I (iodine) are the elements
RR - right reverent - bishop?
Right Reverend
He(lium) + I(odine)

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