It's typical of resin that's oozing out. Wipe as much off as possible with a cloth and methylated spirits - which dissolves resin. Get a can of 'knotting solution' (a kind of varnish) from your DIY store and follow the instructions. This will provide a seal over the resin and allow you to paint normally.
If you like, you can firstly apply a heat gun (without scorching the wood!). This will get more of the resin out.. Otherwise, later, if your gate is facing the sun, the heat from the sun will be enough to cause more resin to bleed out and blister your paintwork.



